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Recent Applications of Photothermal Conversion in Organic Synthesis

Megan E. Matter, Clotilde Tagnon, Erin E. Stache

ACS Cent. Sci. 2024, 10, 8, 1460-1472.

Outlook

Publication Abstract

Photothermal conversion is a novel heating method that has emerged in recent years, wherein certain species can convert light to heat with great efficiency. These photothermal agents have shown immense promise for generating nanoscale thermal gradients under mild, visible light irradiation, providing a pathway for combining photochemistry with thermally driven reactivity. While this novel heating mechanism has been leveraged to great effect for applications such as photothermal therapeutics and steam water purification, it has seen limited use in organic synthesis. This outlook explores instances wherein the photothermal effect was used directly or as a synergistic component to drive organic reactions and postulates how it may be used moving forward.